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{{electromagnetism|Electrostatics}}
The '''electric dipole moment''' is a measure of the separation of positive and negative [[electrical charge]]s within a system, that is, a measure of the system's overall [[Chemical polarity|polarity]].  The [[International System of Units|SI units]] for electric [[dipole]] moment are [[coulomb]]-[[meter]] (C⋅m); however, a commonly used unit in atomic physics and chemistry is the [[debye]] (D).

Theoretically, an electric dipole is defined by the first-order term of the [[multipole expansion]]; it consists of two equal and opposite charges that are infinitesimally close together. This is unrealistic, as real dipoles have separated charge.<ref>Many theorists predict [[elementary particle]]s can have very tiny electric dipole moments, possibly without separated charge. Such large dipoles make no difference to everyday physics, and have not yet been observed. (See [[electron electric dipole moment]]).</ref> However, because the charge separation is very small compared to [[Length scale|everyday lengths]], the error introduced by treating real dipoles like they are theoretically perfect is usually negligible. The dipole's direction usually points from the negative charge towards the positive charge.
Direction is independent of the sides

==Elementary definition==

[[File:Electric dipole moment definition.svg|thumb|Quantities defining the electric dipole moment of two point charges.]]

{{multiple image
 | width    = 250
 | image1   = VFPt dipole animation electric.gif
 | caption1 = Animation showing the [[electric field]] of an electric dipole. The dipole consists of two point electric charges of opposite polarity located close together. A transformation from a point-shaped dipole to a finite-size electric dipole is shown.
 | image2   = Water-elpot-transparent-3D-balls.png
 | caption2 = A [[water molecule|molecule of water]] is polar because of the unequal sharing of its electrons in a "bent" structure. A separation of charge is present with  negative charge in the middle (red shade), and  positive charge at the ends (blue shade).
}}

Often in physics the dimensions of a massive object can be ignored and can be treated as a pointlike object, i.e. a [[point particle]]. Point particles with [[electric charge]] are referred to as [[point charge]]s. Two point charges, one with charge +''q'' and the other one with charge &minus;''q'' separated by a distance ''d'', constitute an ''electric dipole'' (a simple case of an [[Multipole expansion|electric multipole]]). For this case, the electric dipole moment has a magnitude
: <math>p = qd</math>

and is directed from the negative charge to the positive one. Some authors may split ''d'' in half and use ''s'' = ''d''/2 since this quantity is the distance between either charge and the center of the dipole, leading to a factor of two in the definition.

A stronger mathematical definition is to use [[vector algebra]], since a quantity with magnitude and direction, like the dipole moment of two point charges, can be expressed in vector form
: <math>\mathbf{p} = q\mathbf{d}</math>

where '''d''' is the [[displacement (vector)|displacement vector]] pointing from the negative charge to the positive charge. The electric dipole moment vector '''p''' also points from the negative charge to the positive charge.

An idealization of this two-charge system is the electrical point dipole consisting of two (infinite) charges only infinitesimally separated, but with a finite '''p'''.

This quantity is used in the definition of [[polarization density]].
{{Clear}}

==Energy and torque==

[[File:Electric dipole torque uniform field.svg|thumb|187x187px|Electric dipole '''p''' and its torque '''τ''' in a uniform '''E''' field.]]

An object with an electric dipole moment is subject to a [[torque]] ''&tau;'' when placed in an external electric field. The torque tends to align the dipole with the field. A dipole aligned parallel to an electric field has lower [[potential energy]] than a dipole making some angle with it.  For a spatially uniform electric field '''E''', the energy ''U'' and the torque <math>\boldsymbol{\tau}</math> are given by<ref name=Seaway>
{{cite book
 | title=Physics for Scientists and Engineers, Volume 2
 | author1=Raymond A. Serway
 | author2=John W. Jewett Jr.
 | url=https://books.google.com/books?id=1D4VJrWY9ikC&pg=PA756
 | page=756–757
 | isbn=978-1439048399
 | year=2009
 | publisher=Cengage Learning
 |edition= 8th
}}</ref>
:<math>U = - \mathbf{p} \cdot \mathbf{E},\qquad\ \boldsymbol{\tau} = \mathbf{p} \times \mathbf{E},</math>

where '''p''' is the dipole moment, and the symbol "×" refers to the [[vector cross product]]. The field vector and the dipole vector define a plane, and the torque is directed normal to that plane with the direction given by the [[right-hand rule]].

A dipole oriented co- or anti-parallel to the direction in which a non-uniform electric field is  increasing (gradient of the field) will experience a torque, as well as a force in the direction of its dipole moment. It can be shown that this force will always be parallel to the dipole moment regardless of co- or anti-parallel orientation of the dipole.

==Expression (general case)==
More generally, for a continuous distribution of charge confined to a volume ''V'', the corresponding expression for the dipole moment is:
:<math>\mathbf{p}(\mathbf{r}) = \int\limits_{V} \rho(\mathbf{r}_0)\, \left(\mathbf{r}_0 - \mathbf{r}\right) \ d^3 \mathbf{r}_0,</math>

where '''r''' locates the point of observation and ''d''<sup>3</sup>'''r'''<sub>0</sub> denotes an elementary volume in ''V''. For an array of point charges, the charge density becomes a sum of [[Dirac delta function]]s:
:<math>\rho(\mathbf{r}) = \sum_{i=1}^N \, q_i \, \delta \left(\mathbf{r} - \mathbf{r}_i\right),</math>

where each '''r'''<sub>''i''</sub> is a vector from some reference point to the charge ''q<sub>i</sub>''. Substitution into the above integration formula provides:
: <math>\mathbf{p}(\mathbf{r}) =
  \sum_{i=1}^N \, q_i \int\limits_V \delta\left(\mathbf{r}_0 - \mathbf{r}_i\right)\, \left(\mathbf{r}_0 - \mathbf{r}\right)\ d^3 \mathbf{r}_0 =
  \sum_{i=1}^N \, q_i \left(\mathbf{r}_i - \mathbf{r}\right).
</math>

This expression is equivalent to the previous expression in the case of charge neutrality and ''N'' = 2. For two opposite charges, denoting the location of the positive charge of the pair as '''r'''<sub>+</sub> and the location of the negative charge as '''r'''<sub>&minus;</sub> :
: <math>\mathbf{p}(\mathbf{r}) =
  q_1(\mathbf{r}_1 - \mathbf{r}) + q_2(\mathbf{r}_2 - \mathbf{r}) =
  q(\mathbf{r}_+ -\mathbf{r})-q(\mathbf{r}_- - \mathbf{r}) =
  q (\mathbf{r}_+ - \mathbf{r}_-) = q\mathbf{d},
</math>

showing that the dipole moment vector is directed from the negative charge to the positive charge because the [[position vector]] of a point is directed outward from the origin to that point.

The dipole moment is particularly useful in the context of an overall neutral system of charges, for example a pair of opposite charges, or a neutral conductor in a uniform electric field. 
For such a system of charges, visualized as an array of paired opposite charges, the relation for electric dipole moment is:

:<math>\begin{align}
  \mathbf{p}(\mathbf{r})
    &= \sum_{i=1}^N\, \int\limits_V q_i \left[\delta \left(\mathbf{r}_0 - \left(\mathbf{r}_i + \mathbf{d}_i\right)\right) - \delta\left(\mathbf{r}_0 - \mathbf{r}_i\right)\right]\, \left(\mathbf{r}_0 - \mathbf{r}\right)\ d^3 \mathbf{r}_0 \\
    &= \sum_{i=1}^N\, q_i\, \left[\mathbf{r}_i + \mathbf{d}_i - \mathbf{r} - \left(\mathbf{r}_i - \mathbf{r}\right)\right] \\
    &= \sum_{i=1}^N q_i \mathbf{d}_i = \sum_{i=1}^{N} \mathbf{p}_i \ , 
\end{align}</math>

where '''r''' is the point of observation, and '''d'''<sub>''i''</sub> = '''r'''<sub>''i''</sub> − '''r{{'}}'''<sub>''i''</sub>, '''r'''<sub>''i''</sub> being the position of the positive charge in the dipole ''i'', and '''r{{'}}'''<sub>''i''</sub> the position of the negative charge.
This is the [[vector sum]] of the individual dipole moments of the neutral charge pairs. (Because of overall charge neutrality, the dipole moment is independent of the observer's position '''r'''.) Thus, the value of '''p''' is independent of the choice of reference point, provided the overall charge of the system is zero.

When discussing the dipole moment of a non-neutral system, such as the dipole moment of the [[proton]], a dependence on the choice of reference point arises.  In such cases it is conventional to choose the reference point to be the [[center of mass]] of the system, not some arbitrary origin.<ref name=Cramer>{{cite book
 | title=Essentials of computational chemistry
 | author=Christopher J. Cramer
 | url=https://books.google.com/books?id=tNiyZjAZqKkC&pg=PA307
 | isbn=978-0-470-09182-1
 | publisher=Wiley
 | year=2004
 | edition= 2nd
 | page=307
}}</ref>  This choice is not only a matter of convention: the notion of dipole moment is essentially derived from the mechanical notion of torque, and as in mechanics, it is computationally and theoretically useful to choose the center of mass as the observation point.  For a charged molecule the center of charge should be the reference point instead of the center of mass. For neutral systems the references point is not important. The dipole moment is an [[intrinsic property]] of the system.

==Potential and field of an electric dipole==
[[File:DipolePotential.tiff|thumbnail|An electric dipole potential map. Negative potentials are in blue; positive potentials, in red.]]

An ideal dipole consists of two opposite charges with infinitesimal separation. The potential and field of such an ideal dipole are found next as a limiting case of an example of two opposite charges at non-zero separation.

Two closely spaced opposite charges have a potential of the form:
:<math>\phi(\mathbf{r}) = \frac{q}{4 \pi \varepsilon _0 \left|\mathbf{r} - \mathbf{r}_+\right|} - \frac{q}{4 \pi \varepsilon _0 \left|\mathbf{r} - \mathbf{r}_-\right|}\ ,</math>

with charge separation, d, defined as
:<math>\mathbf{d} = \mathbf{r}_+ - \mathbf{r}_-\ ,</math>

The position relative to their center of mass (assuming equal masses), '''R''', and the unit vector in the direction of '''R''' are given by:
:<math>\mathbf{R} = \mathbf{r} - \frac{\mathbf{r}_+ + \mathbf{r}_-}{2}, \quad \hat{\mathbf{R}} = \frac{\mathbf{R}}{R}\ ,</math>

Taylor expansion in ''d''/''R'' (see [[multipole expansion]] and [[quadrupole#electric quadrupole|quadrupole]]) allows this potential to be expressed as a series.<ref name=Dugdale>

{{cite book |title=Essentials of Electromagnetism |author=David E Dugdale |pages= 80–81 |url=https://books.google.com/books?id=LIwBcIwrwv4C&pg=PA81 |isbn=978-1-56396-253-0 |year=1993 |publisher=Springer}}</ref><ref name=Hirose>{{cite book |title=First-principles calculations in real-space formalism |author1=Kikuji Hirose |author2=Tomoya Ono |author3=Yoshitaka Fujimoto |url=https://books.google.com/books?id=TkvogLqVrqwC&pg=PA18 |page=18 |publisher=Imperial College Press |year=2005 |isbn=978-1-86094-512-0}}</ref>
:<math>\phi(\mathbf{R}) = \frac{1}{4 \pi \varepsilon _0} \frac{q\mathbf{d} \cdot \hat{\mathbf{R}}}{R^2} + O\left(\frac{d^2}{R^2}\right) \approx \frac{1}{4 \pi \varepsilon _0} \frac{\mathbf{p} \cdot \hat{\mathbf{R}}}{R^2}\ ,</math>

where higher order terms in the series are vanishing at large distances, ''R'', compared to ''d''.<ref name=Quadrapole>

Each succeeding term provides a more detailed view of the distribution of charge, and falls off more rapidly with distance. For example, the ''[[Quadrupole#electric quadrupole|quadrupole moment]]'' is the basis for the next term:
: <math>Q_{ij} = \int d^3 \mathbf{r}_0 \left(3 x_i x_j - r_0^2 \delta_{ij}\right) \rho\left(\mathbf{r}_0\right)\ ,</math>

with '''r<sub>0</sub>''' = (x<sub>1</sub>, x<sub>2</sub>, x<sub>3</sub>). See {{cite book
 |author=HW Wyld
 |url=https://books.google.com/books?id=Uy8xRd5_7tsC&pg=PA103
 |title=Mathematical Methods for Physics
 |page=106
 |isbn=978-0-7382-0125-2
 |year=1999
 |publisher=Westview Press
}}</ref> Here, the electric dipole moment '''p''' is, as above:
:<math>\mathbf{p} = q\mathbf{d}\ .</math>

The result for the dipole potential also can be expressed as:<ref name=Laud>{{cite book |author=BB Laud |title=Electromagnetics |url=https://books.google.com/books?id=XtgFvbd9F2UC&pg=PA25 |page=25 |isbn=978-0-85226-499-7 |year=1987 |edition= 2nd |publisher=New Age International}}</ref>
:<math>\phi(\mathbf{R}) = -\mathbf{p} \cdot \mathbf{\nabla} \frac{1}{4 \pi \varepsilon _0 R}\ ,</math>

which relates the dipole potential to that of a point charge. A key point is that the potential of the dipole falls off faster with distance ''R'' than that of the point charge.

The electric field of the dipole is the negative gradient of the potential, leading to:<ref name=Laud/>
:<math>\mathbf E\left(\mathbf R\right) = \frac{3\left(\mathbf{p} \cdot \hat{\mathbf{R}}\right) \hat{\mathbf{R}} - \mathbf{p}}{4 \pi \varepsilon_0 R^3}\ .</math>

Thus, although two closely spaced opposite charges are ''not quite'' an ideal electric dipole (because their potential at short distances is not that of a dipole), at distances much larger than their separation, their dipole moment '''p''' appears directly in their potential and field.

As the two charges are brought closer together (''d'' is made smaller), the dipole term in the multipole expansion based on the ratio ''d''/''R'' becomes the only significant term at ever closer distances ''R'', and in the limit of infinitesimal separation the dipole term in this expansion is all that matters. As ''d'' is made infinitesimal, however, the dipole charge must be made to increase to hold '''p''' constant. This limiting process results in a "point dipole".

==Dipole moment density and polarization density==

The dipole moment of an array of charges, 
:<math>\mathbf p = \sum_{i=1}^N \ q_i \mathbf {d_i} \ , </math>

determines the degree of polarity of the array, but for a neutral array it is simply a vector property of the array with no information about the array's absolute location. The dipole moment ''density'' of the array '''p'''('''r''') contains both the location of the array and its dipole moment. When it comes time to calculate the electric field in some region containing the array, Maxwell's equations are solved, and the information about the charge array is contained in the ''polarization density'' '''P'''('''r''') of Maxwell's equations. Depending upon how fine-grained an assessment of the electric field is required, more or less information about the charge array will have to be expressed by '''P'''('''r'''). As explained below, sometimes it is sufficiently accurate to take '''P'''('''r''') = '''p'''('''r'''). Sometimes a more detailed description is needed (for example, supplementing the dipole moment density with an additional quadrupole density) and sometimes even more elaborate versions of '''P'''('''r''') are necessary.

It now is explored just in what way the polarization density '''P'''('''r''') that enters [[Maxwell's equations]] is related to the dipole moment '''p''' of an overall neutral array of charges, and also to the ''dipole moment density'' '''p'''('''r''') (which describes not only the dipole moment, but also the array location). Only static situations are considered in what follows, so '''P(r)''' has no time dependence, and there is no [[displacement current]]. First is some discussion of the polarization density '''P'''('''r'''). That discussion is followed with several particular examples.

A formulation of [[Maxwell's equations]] based upon division of charges and currents into "free" and "bound" charges and currents leads to introduction of the '''D'''- and '''P'''-fields:
:<math> \mathbf{D} = \varepsilon _0 \mathbf{E} + \mathbf{P}\ , </math>

where '''P''' is called the [[polarization density]]. In this formulation, the divergence of this equation yields:
:<math>\nabla \cdot \mathbf{D} = \rho_f = \varepsilon _0 \nabla \cdot \mathbf{E} +\nabla \cdot \mathbf{P}\ , </math>

and as the divergence term in '''E''' is the ''total'' charge, and ''ρ<sub>f</sub>'' is "free charge", we are left with the relation:
:<math>\nabla \cdot \mathbf{P} = -\rho_b \ , </math>

with ''ρ<sub>b</sub>'' as the bound charge, by which is meant the difference between the total and the free charge densities.

As an aside, in the absence of magnetic effects, Maxwell's equations specify that
:<math>\nabla \times \mathbf{E} = \boldsymbol{0}\ ,</math>

which implies
:<math>\nabla \times \left( \mathbf{D} - \mathbf{P} \right) = \boldsymbol{0}\ ,</math>

Applying [[Helmholtz decomposition]]:<ref name=Wu>
{{cite book
 | title=Vorticity and vortex dynamics
 | author1=Jie-Zhi Wu
 | author2=Hui-Yang Ma
 | author3=Ming-De Zhou
 | pages=36 ''ff''
 | chapter-url=https://books.google.com/books?id=P5yNCu44PiwC&pg=PA36
 | chapter=§2.3.1 Functionally Orthogonal Decomposition
 | isbn=978-3-540-29027-8
 | year=2006
 | publisher=Springer
}}</ref>
:<math> \mathbf{ D-P = -\nabla } \varphi \ , </math>

for some scalar potential ''φ'', and:
: <math>\nabla \cdot (\mathbf{D} - \mathbf{P}) = \varepsilon_0 \nabla \cdot \mathbf{E} = \rho_f + \rho_b = - \nabla^2 \varphi\ .</math>

Suppose the charges are divided into free and bound, and the potential is divided into

:<math>\varphi = \varphi_f + \varphi_b\ .</math>

Satisfaction of the boundary conditions upon ''φ'' may be divided arbitrarily between ''φ<sub>f</sub>'' and ''φ<sub>b</sub>'' because only the sum ''φ'' must satisfy these conditions.  It follows that '''P''' is simply proportional to the electric field due to the charges selected as bound, with boundary conditions that prove convenient.<ref name=Laplacian>

For example, one could place the boundary around the bound charges at infinity. Then ''φ<sub>b</sub>'' falls off with distance from the bound charges. If an external field is present, and zero free charge, the field can be accounted for in the contribution  of ''φ<sub>f</sub>'', which would arrange to satisfy the boundary conditions and [[Laplace's equation]]
:<math>\nabla^2 \varphi_f = 0\ .</math>
</ref><ref name=curl>

In principle, one could add the same arbitrary ''curl'' to both '''D''' and '''P''', which would cancel out of the difference '''D''' − '''P'''. However, assuming '''D''' and '''P''' originate in a simple division of charges into free and bound, they a formally similar to electric fields and so have zero ''curl''.

</ref> In particular, when ''no'' free charge is present, one possible choice is '''P''' = ''ε''<sub>0</sub> '''E'''.

Next is discussed how several different dipole moment descriptions of a medium relate to the polarization entering Maxwell's equations.

===Medium with charge and dipole densities===
As described next, a model for polarization moment density '''p'''('''r''') results in a polarization

:<math>\mathbf{P}(\mathbf{r}) = \mathbf{p}(\mathbf{r}) \, </math>

restricted to the same model. For a smoothly varying dipole moment distribution '''p'''('''r'''), the corresponding bound charge density is simply

:<math>\nabla \cdot \mathbf{p} (\mathbf{r}) = \rho_b,</math>

as we will establish shortly via [[integration by parts]]. However, if '''p'''('''r''') exhibits an abrupt step in dipole moment at a boundary between two regions, ∇·'''p'''('''r''') results in  a surface charge component of bound charge. This surface charge can be treated through a [[surface integral]], or by using discontinuity conditions at the boundary, as illustrated in the various examples below.

As a first example relating dipole moment to polarization, consider a medium made up of a continuous charge density ''ρ''('''r''') and a continuous dipole moment distribution '''p'''('''r''').<ref name=Vanderlinde>

This medium can be seen as an idealization growing from the multipole expansion of the potential of an arbitrarily complex charge distribution, truncation of the expansion, and the forcing of the truncated form to apply everywhere. The result is a hypothetical medium. See {{cite book
 | title=Classical Electromagnetic Theory
 | author=Jack Vanderlinde
 | chapter-url=https://books.google.com/books?id=HWrMET9_VpUC&pg=PA165
 | chapter=§7.1 The electric field due to a polarized dielectric
 | isbn=978-1-4020-2699-7
 | publisher=Springer
 | year=2004
}}</ref> The potential at a position '''r''' is:<ref name=Krey>
{{cite book
 |title=Basic Theoretical Physics: A Concise Overview
 |author1=Uwe Krey
 |author2=Anthony Owen
 |pages = 138–143
 |isbn=978-3-540-36804-5
 |publisher=Springer|year=2007
 |url=https://books.google.com/books?id=xZ_QelBmkxYC&pg=PA327&dq=isbn=3540368043#PPA138,M1
}}</ref><ref name=Tsang>
{{cite book
 |title=Classical Electrodynamics
 |url=https://books.google.com/books?id=KQe5QJ9PJwMC&pg=PA59
 |page=59
 |author=T Tsang
 |isbn=978-981-02-3041-8
 |publisher=World Scientific
 |year=1997
}}</ref>
:<math>\phi (\mathbf{r}) = \frac{1}{4 \pi \varepsilon_0} \int \frac{\rho \left(\mathbf{r}_0\right)}{\left|\mathbf{r} - \mathbf{r}_0\right|} d^3 \mathbf{r}_0 \ + \frac {1}{4 \pi \varepsilon_0}\int \frac{\mathbf{p} \left(\mathbf{r}_0\right) \cdot \left(\mathbf{r} - \mathbf{r}_0\right)} {| \mathbf{r} - \mathbf{r}_0 |^3 } d^3 \mathbf{ r}_0 , </math>

where ''ρ''('''r''') is the unpaired charge density, and '''p'''('''r''') is the dipole moment density.<ref name=density>

For example, for a system of ideal dipoles with dipole moment '''p''' confined within some closed surface, the ''dipole density'' '''p'''('''r''') is equal to '''p''' inside the surface, but is zero outside. That is, the dipole density includes a [[Heaviside step function]] locating the dipoles inside the surface.

</ref> Using an identity:
: <math>\nabla_{\mathbf{r}_0} \frac{1}{\left|\mathbf{r} - \mathbf{r}_0\right|} = \frac{\mathbf{r} - \mathbf{r}_0}{\left|\mathbf{r} - \mathbf{r}_0\right|^3}</math>

the polarization integral can be transformed:
: <math>\begin{align}
      &\frac{1}{4 \pi \varepsilon_0} \int \frac{\mathbf{p} \left(\mathbf{r}_0\right) \cdot (\mathbf{r} - \mathbf{r}_0)}{\left|\mathbf{r} - \mathbf{r}_0\right|^3 } d^3 \mathbf{ r}_0 = 
         \frac {1}{4 \pi \varepsilon_0}\int \mathbf{p} \left(\mathbf{r}_0\right) \cdot \nabla_{\mathbf{r}_0} \frac{1}{\left|\mathbf{r} - \mathbf{r}_0\right|} d^3 \mathbf{r}_0 , \\
  ={} &\frac{1}{4 \pi \varepsilon_0} \int \nabla_{\mathbf{r}_0} \cdot \left(\mathbf{p} \left(\mathbf{r}_0\right) \frac {1}{\left|\mathbf{r} -
         \mathbf{r}_0\right|}\right) d^3 \mathbf{r}_0 - \frac{1}{4 \pi \varepsilon_0} \int \frac{\nabla_{\mathbf{r}_0} \cdot \mathbf{p} \left(\mathbf{r}_0\right)}{\left|\mathbf{r} - \mathbf{r}_0\right|} d^3 \mathbf{r}_0 ,
\end{align}</math>

The first term can be transformed to an integral over the surface bounding the volume of integration, and contributes a surface charge density, discussed later.  Putting this result back into the potential, and ignoring the surface charge for now:
:<math>\phi (\mathbf{r}) = \frac{1}{4 \pi \varepsilon_0} \int \frac{\rho \left(\mathbf{r}_0\right) - \nabla_{\mathbf{r}_0} \cdot \mathbf{p} \left(\mathbf{r}_0\right)}{\left|\mathbf{r} - \mathbf{r}_0\right|} d^3 \mathbf{r}_0\ ,</math>

where the volume integration extends only up to the bounding surface, and does not include this surface.

The potential is determined by the total charge, which the above shows consists of:
:<math>\rho_\text{total} \left(\mathbf{r}_0\right) =  \rho\left(\mathbf{r}_0\right) - \nabla_{\mathbf{r}_0} \cdot \mathbf{p} \left(\mathbf{r}_0\right)\ ,</math>

showing that:
:<math>-\nabla_{\mathbf{r}_0} \cdot \mathbf{p} \left(\mathbf{r}_0\right) = \rho_b\ .</math>

In short, the dipole moment density '''p'''('''r''') plays the role of the polarization density '''P''' for this medium. Notice, '''p'''('''r''') has a non-zero divergence equal to the bound charge density (as modeled in this approximation).

It may be noted that this approach can be extended to include all the  multipoles: dipole, quadrupole, etc.<ref name=Owen>
{{cite book
 |title= Introduction to Electromagnetic Theory
 |author=George E Owen
 |url=https://books.google.com/books?id=VLm_dqhZUOYC&pg=PA80
 |page=80
 |isbn=978-0-486-42830-7
 |publisher=Courier Dover Publications
 |year=2003
 |edition= republication of the 1963 Allyn & Bacon
}}</ref><ref name=Brevet>
{{cite book
 |title=Surface second harmonic generation
 |author=Pierre-François Brevet
 |url=https://books.google.com/books?id=_clt5ZowQYsC&pg=PA24
 |page=24
 |isbn=978-2-88074-345-1
 |year=1997
 |publisher=[[Presses polytechniques et universitaires romandes]]
}}</ref> Using the relation:
:<math>\nabla \cdot \mathbf{D} = \rho_f \ ,</math>

the polarization density is found to be:
:<math>\mathbf{P}(\mathbf{r}) = \mathbf{p}_\text{dip} - \nabla \cdot \mathbf{p}_\text{quad} + \ldots\ ,</math>

where the added terms are meant to indicate contributions from higher multipoles. Evidently, inclusion of higher multipoles signifies that the polarization density '''P''' no longer is determined by a dipole moment density '''p''' alone. For example, in considering scattering from a charge array, different multipoles scatter an electromagnetic wave differently and independently, requiring a representation of the charges that goes beyond the dipole approximation.<ref name=multipole2>

See {{cite book |isbn=978-981-02-3325-9 |url=https://books.google.com/books?id=NUv5csOQBGAC&pg=PA219  |title=Computational studies of new materials |author1=Daniel A. Jelski |author2=Thomas F. George |page=219 |year=1999 |publisher=World Scientific}} and {{cite journal |author1=EM Purcell |author2=CR Pennypacker |journal=Astrophysical Journal |title= Scattering and Absorption of Light by Nonspherical Dielectric Grains |volume=186 |pages= 705–714 |year=1973 |bibcode=1973ApJ...186..705P |doi=10.1086/152538 }}</ref>

====Surface charge====
[[File:Dipole polarization.JPG|thumb|A uniform array of identical dipoles is equivalent to a surface charge.]]
Above, discussion was deferred for the first term in the expression for the potential due to the dipoles. Integrating the divergence results in a surface charge. The figure at the right provides an intuitive idea of why a surface charge arises. The figure shows a uniform array of identical dipoles between two surfaces. Internally, the heads and tails of dipoles are adjacent and cancel. At the bounding surfaces, however, no cancellation occurs. Instead, on one surface the dipole heads create a positive surface charge, while at the opposite surface the dipole tails create a negative surface charge. These two opposite surface charges create a net electric field in a direction opposite to the direction of the dipoles.

This idea is given mathematical form using the potential expression above. The potential is:
:<math>
  \phi\left(\mathbf{r}\right) =
    \frac{1}{4 \pi \varepsilon_0} \int \nabla_{\mathbf{r}_0} \cdot \left(\mathbf{p} \left(\mathbf{r}_0\right) \frac{1}{\left|\mathbf{r} - \mathbf{r}_0\right|} \right) d^3 \mathbf{r}_0 -
    \frac{1}{4 \pi \varepsilon_0} \int \frac{\nabla_{\mathbf{r}_0} \cdot \mathbf{p} \left(\mathbf{r}_0\right)}{\left|\mathbf{r} - \mathbf{r}_0\right|} d^3 \mathbf{r}_0\ .
</math>

Using the [[divergence theorem]], the divergence term transforms into the surface integral:
:<math>\begin{align}
      &\frac{1}{4 \pi \varepsilon_0} \int \nabla_{\mathbf{r}_0} \cdot \left(\mathbf{p} \left(\mathbf{r}_0\right) \frac{1}{\left|\mathbf{r} - \mathbf{r}_0\right|}\right) d^3\mathbf{r}_0 \\
  ={} &\frac{1}{4 \pi \varepsilon_0} \int \frac{\mathbf{p} \left(\mathbf{r}_0\right) \cdot d \mathbf{A}_0}\left|\mathbf{r} - \mathbf{r}_0\right| \ ,
\end{align}</math>

with d'''A'''<sub>0</sub> an element of surface area of the volume. In the event that '''p'''('''r''') is a constant, only the surface term survives:
:<math>\phi(\mathbf{r}) = \frac{1}{4 \pi \varepsilon_0} \int \frac{1}{\left|\mathbf{r} - \mathbf{r}_0\right|}\ \mathbf{p} \cdot d\mathbf{A}_0 \ ,</math>

with d'''A'''<sub>0</sub> an elementary area of the surface bounding the charges. In words, the potential due to a constant '''p''' inside the surface is equivalent to that of a ''surface charge''
:<math>\sigma = \mathbf{p} \cdot d \mathbf{A}</math>

which is positive for surface elements with a component in the direction of '''p''' and negative for surface elements pointed oppositely. (Usually the direction of a surface element is taken to be that of the outward normal to the surface at the location of the element.)

If the bounding surface is a sphere, and the point of observation is at the center of this sphere, the integration over the surface of the sphere is zero: the positive and negative surface charge contributions to the potential cancel. If the point of observation is off-center, however, a net potential can result (depending upon the situation) because the positive and negative charges are at different distances from the point of observation.<ref name = multipole1>

A brute force evaluation of the integral can be done using a multipole expansion: <math>
  \frac{1}{\left|\mathbf{r} - \mathbf{r}_0\right|} = \sum_{\ell,\ m}
    \frac{4\pi}{2\ell + 1} \frac{1}{r} \left(\frac{r_0}{r}\right)^\ell
    {Y^*}_{\ell}^m \left(\theta_0,\ \phi_0\right)
        Y_{\ell}^m \left(\theta,\ \phi\right)
</math>. See {{cite book
 | title=Mathematical Methods for Physics
 | author=HW Wyld
 | page=104
 | url=https://books.google.com/books?id=Uy8xRd5_7tsC&pg=PA104
 | isbn=978-0-7382-0125-2
 | year=1999
 | publisher=Westview Press
}}</ref> The field due to the surface charge is:
:<math>\mathbf{E}\left(\mathbf{r}\right) = -\frac{1}{4 \pi \varepsilon_0} \nabla_\mathbf{r} \int \frac{1}{\left|\mathbf{r} - \mathbf{r}_0\right|}\ \mathbf{p} \cdot d\mathbf{A}_0\ ,</math>

which, at the center of a spherical bounding surface is not zero (the ''fields'' of negative and positive charges on opposite sides of the center add because both fields point the same way) but is instead:<ref name=Ibach/>
::<math>\mathbf{E} = -\frac{\mathbf{p}}{3 \varepsilon_0}\ .</math>

If we suppose the polarization of the dipoles was induced by an external field, the polarization field opposes the applied field and sometimes is called a ''depolarization field''.<ref name=Takagahara>
{{cite book
 | title=Semiconductor quantum dots: physics, spectroscopy, and applications
 | author1=Yasuaki Masumoto
 | author2=Toshihide Takagahara
 | publisher=Springer
 | year=2002
 | isbn=978-3-540-42805-3
 | page=72
 | url=https://books.google.com/books?id=eacszlpNisgC&pg=PA72
}}</ref><ref name=Toyozawa>
{{cite book
 | author=Yutaka Toyozawa
 | title=Optical processes in solids
 | url=https://books.google.com/books?id=IGkSP2y8V7MC&pg=PA96
 | page=96
 | isbn=978-0-521-55605-7
 | publisher=Cambridge University Press
 | year=2003
}}</ref> In the case when the polarization is ''outside'' a spherical cavity, the field in the cavity due to the surrounding dipoles is in the ''same'' direction as the polarization.<ref name= Drzaic>

For example, a droplet in a surrounding medium experiences a higher or a lower internal field depending upon whether the medium has a higher or a lower dielectric constant than that of the droplet. See {{cite book
 |title=Liquid crystal dispersions
 |author=Paul S. Drzaic
 |url=https://books.google.com/books?id=FyPKhF15KEAC&pg=PA246
 |page=246
 |isbn=978-981-02-1745-7
 |year=1995
 |publisher=World Scientific
}}</ref>

In particular, if the [[electric susceptibility]] is introduced through the approximation:
:<math>\mathbf{p}(\mathbf{r}) = \varepsilon_0 \chi(\mathbf{r}) \mathbf{E}(\mathbf{r})\ ,</math>

where '''''E''''', in this case and in the following, represent the ''external field'' which induces the polarization.

Then:
:<math>\nabla \cdot \mathbf{p}(\mathbf{r}) = \nabla \cdot \left(\chi(\mathbf{r}) \varepsilon_0 \mathbf{E}(\mathbf{r})\right) = -\rho_b\ .</math>

Whenever ''χ''('''r''') is used to model a step discontinuity at the boundary between two regions, the step produces a surface charge layer. For example, integrating along a normal to the bounding surface from a point just interior to one surface to another point just exterior:
:<math>\varepsilon_0 \hat{\mathbf{n}} \cdot \left[\chi\left(\mathbf{r}_+\right) \mathbf{E}\left(\mathbf{r}_+\right) - \chi\left(\mathbf{r}_-\right) \mathbf{E}\left(\mathbf{r}_-\right)\right] = \frac{1}{A_n} \int d \Omega_n\ \rho_b = 0\ ,</math>

where ''A''<sub>n</sub>, ''Ω''<sub>n</sub> indicate the area and volume of an elementary region straddling the boundary between the regions, and <math>\hat{\mathbf{n}}</math> a unit normal to the surface. The right side vanishes as the volume shrinks, inasmuch as ρ<sub>b</sub> is finite, indicating a discontinuity in '''''E''''', and therefore a surface charge. That is, where the modeled medium includes a step in permittivity, the polarization density corresponding to the dipole moment density
:<math>\mathbf{p}(\mathbf{r}) = \chi(\mathbf{r}) \mathbf{E}(\mathbf{r})</math>

necessarily includes the contribution of a surface charge.<ref name=Chen>
{{cite book
 | title=The electrical engineering handbook
 | page=502
 | author=Wai-Kai Chen
 | url=https://books.google.com/books?id=qhHsSlazGrQC&pg=PA502
 | isbn=978-0-12-170960-0
 | year=2005
 | publisher=Academic Press
}}</ref><ref name=Stratton2>
{{cite book
 | title=Electromagnetic theory
 | url=https://books.google.com/books?id=zFeWdS2luE4C&pg=PA184
 | author=Julius Adams Stratton
 | page= 184
 | year=2007
 | isbn=978-0-470-13153-4
 | publisher=Wiley-IEEE
 | edition= reprint of 1941
}}</ref><ref name=Cloud>
{{cite book
 | url=https://books.google.com/books?id=jCqv1UygjA4C&pg=PA68
 | page=68
 | author1=Edward J. Rothwell
 | author2=Michael J. Cloud
 | title=Electromagnetics
 | isbn=978-0-8493-1397-4
 | year=2001
 | publisher=CRC Press
}}</ref>

A physically more realistic modeling of '''p'''('''r''') would have the dipole moment density drop off rapidly, but smoothly to zero at the boundary of the confining region, rather than making a sudden step to zero density. Then the surface charge will not concentrate in an infinitely thin surface, but instead, being the divergence of a smoothly varying dipole moment density, will distribute itself throughout a thin, but finite transition layer.

====Dielectric sphere in uniform external electric field====
[[File:Dielectric sphere.JPG|thumb|250px|[[Field line]]s of the [[electric displacement field|'''D'''-field]] in a dielectric sphere with greater susceptibility than its surroundings, placed in a previously-uniform field.<ref name=Gray>Based upon equations from {{cite book |title=The theory and practice of absolute measurements in electricity and magnetism |author=Andrew Gray |year=1888 |publisher=Macmillan & Co. |pages= 126–127 |url=https://books.google.com/books?id=jb0KAAAAIAAJ&pg=PA127}}, which refers to papers by Sir W. Thomson.</ref> The [[field line]]s of the [[electric field|'''E'''-field]] (not shown) coincide everywhere with those of the '''D'''-field, but inside the sphere, their density is lower, corresponding to the fact that the '''E'''-field is weaker inside the sphere than outside. Many of the external '''E'''-field lines terminate on the surface of the sphere, where there is a bound charge.]]

The above general remarks about surface charge are made more concrete by considering the example of a dielectric sphere in a uniform electric field.<ref name=Wyld>
{{cite book
 | title=Mathematical Methods for Physics
 | author=HW Wyld
 | url=https://books.google.com/books?id=Uy8xRd5_7tsC&pg=PA233
 | isbn=978-0-7382-0125-2
 | edition= 2nd
 | publisher=Westview Press
 | year=1999
 | pages=233 ''ff''
}}</ref><ref name=Stratton>
{{cite book
 | title=Electromagnetic theory
 | url=https://books.google.com/books?id=zFeWdS2luE4C&pg=PA205
 | page=205 ''ff''
 | author=Julius Adams Stratton
 | isbn=978-0-470-13153-4
 | edition= Wiley-IEEE reissue
 | year=2007
 | publisher=IEEE Press
 | location=Piscataway, NJ
}}</ref> The sphere is found to adopt a surface charge related to the dipole moment of its interior.

A uniform external electric field is supposed to point in the ''z''-direction, and spherical-polar coordinates are introduced so the potential created by this field is:
:<math>\phi_\infty = -E_\infty z = -E_\infty r \cos\theta\ .</math>

The sphere is assumed to be described by a [[Relative static permittivity|dielectric constant]] ''κ'', that is,
:<math>\mathbf{D} = \kappa \epsilon_0 \mathbf{E}\ ,</math>

and inside the sphere the potential satisfies Laplace's equation. Skipping a few details, the solution inside the sphere is:
:<math>\phi_< = A r \cos\theta\ ,</math>

while outside the sphere:
:<math>\phi_> = \left(Br + \frac{C}{r^2} \right) \cos\theta\ .</math>

At large distances, φ<sub>></sub> → φ<sub>∞ </sub> so ''B'' = −''E<sub>∞ </sub>''. Continuity of potential and of the radial component of displacement '''''D''''' = κε<sub>0</sub>'''''E''''' determine the other two constants. Supposing the radius of the sphere is ''R'',
:<math>A = -\frac{3}{\kappa + 2} E_\infty\ ;\ C = \frac{\kappa - 1}{\kappa + 2} E_\infty R^3\ ,</math>

As a consequence, the potential is:
:<math>\phi_> = \left(-r + \frac{\kappa - 1}{\kappa + 2} \frac{R^3}{r^2}\right) E_\infty \cos\theta\ ,</math>

which is the potential due to applied field and, in addition, a dipole in the direction of the applied field (the ''z''-direction) of dipole moment:
:<math>\mathbf{p} = 4 \pi \varepsilon_0 \left(\frac{\kappa - 1}{\kappa + 2} R^3\right) \mathbf{E}_\infty\ ,</math>

or, per unit volume:
:<math>\frac{\mathbf{p}}{V} = 3 \varepsilon_0 \left(\frac{\kappa - 1}{\kappa + 2}\right) \mathbf{E}_\infty\ .</math>

The factor (''κ'' − 1)/(''κ'' + 2) is called the [[Clausius–Mossotti relation|Clausius–Mossotti factor]] and shows that the induced polarization flips sign if ''κ'' < 1. Of course, this cannot happen in this example, but in an example with two different dielectrics ''κ'' is replaced by the ratio of the inner to outer region dielectric constants, which can be greater or smaller than one. The potential inside the sphere is:
:<math>\phi_< = -\frac{3}{\kappa + 2} E_\infty r \cos\theta\ ,</math>

leading to the field inside the sphere:
:<math>-\nabla \phi_< = \frac{3}{\kappa + 2} \mathbf{E}_\infty = \left(1 - \frac{\kappa - 1}{\kappa + 2}\right)\mathbf{ E}_\infty\ ,</math>

showing the depolarizing effect of the dipole. Notice that the field inside the sphere is ''uniform'' and parallel to the applied field. The dipole moment is uniform throughout the interior of the sphere. The surface charge density on the sphere is the difference between the radial field components:
:<math>\sigma = 3 \varepsilon_0 \frac{\kappa - 1}{\kappa + 2} E_\infty \cos\theta = \frac{1}{V} \mathbf{p} \cdot \hat{\mathbf{R}}\ .</math>

This linear dielectric example shows that the dielectric constant treatment is equivalent to the uniform dipole moment model and leads to zero charge everywhere except for the surface charge at the boundary of the sphere.

===General media===
If observation is confined to regions sufficiently remote from a system of charges, a multipole expansion of the exact polarization density can be made. By truncating this expansion (for example, retaining only the dipole terms, or only the dipole and quadrupole terms, or ''etc.''), the results of the previous section are regained. In particular, truncating the expansion at the dipole term, the result is indistinguishable from the polarization density generated by a uniform dipole moment confined to the charge region. To the accuracy of this dipole approximation, as shown in the previous section, the dipole moment ''density'' '''p'''('''r''') (which includes not only '''p''' but the location of '''p''') serves as '''P'''('''r''').

At locations ''inside'' the charge array, to connect an array of paired charges to an approximation involving only a dipole moment density '''p'''('''r''') requires additional considerations. The simplest approximation is to replace the charge array with a model of ideal (infinitesimally spaced) dipoles. In particular, as in the example above that uses a constant dipole moment density confined to a finite region, a surface charge and depolarization field results. A more general version of this model (which allows the polarization to vary with position) is the customary approach using [[electric susceptibility]] or [[electrical permittivity]].

A more complex model of the point charge array introduces an [[Effective medium approximations|effective medium]] by averaging the microscopic charges;<ref name=Toyozawa/> for example, the averaging can arrange that only dipole fields play a role.<ref name=Shalaev>
{{cite book
 | title=Optical properties of nanostructured random media
 | author1=John E Swipe
 | author2=RW Boyd
 | chapter=Nanocomposite materials for nonlinear optics based upon local field effects |editor=Vladimir M. Shalaev
 | chapter-url=https://books.google.com/books?id=OPEBoaI7c1wC&pg=PA3
 | page=3
 | isbn=978-3-540-42031-6
 | year=2002
 | publisher=Springer
}}</ref><ref name=Wolf>
{{cite book
 | title=Progress in Optics
 | author=Emil Wolf |page=288
 | url =https://books.google.com/books?id=yZCqqh3Fr9kC&pg=PA288
 | isbn=978-0-7204-1515-5
 | year=1977
 | publisher=Elsevier
}}</ref> A related approach is to divide the charges into those nearby the point of observation, and those far enough away to allow a multipole expansion. The nearby charges then give rise to ''local field effects''.<ref name=Ibach>
{{cite book
 | title=Solid-state Physics: an introduction to principles of materials science
 | author1=H. Ibach
 | author2=Hans Lüth
 | url=https://books.google.com/books?id=PIEfweaKyK8C&pg=PA361
 | page=361
 | isbn=978-3-540-43870-0
 | publisher=Springer
 | year=2003
 | edition= 3rd
}}</ref><ref name=Fox>
{{cite book
 | url=https://books.google.com/books?id=-5bVBbAoaGoC&pg=PA39
 | page=39
 | author=Mark Fox
 | title=Optical Properties of Solids
 | isbn=978-0-19-850612-6
 | year=2006
 | publisher=Oxford University Press
}}</ref> In a common model of this type, the distant charges are treated as a homogeneous medium using a dielectric constant, and the nearby charges are treated only in a dipole approximation.<ref name=Kantorovich>
{{cite book
 | title=Quantum theory of the solid state
 | author= Lev Kantorovich
 | chapter-url=https://books.google.com/books?id=YoI2-QvDoUAC&pg=PA426
 | page=426
 | chapter=§8.2.1 The local field
 | isbn=978-1-4020-2153-4
 | year=2004
 | publisher=Springer
}}</ref> The approximation of a medium or an array of charges by only dipoles and their associated dipole moment density is sometimes called the ''point dipole'' approximation, the ''[[discrete dipole approximation]]'', or simply the ''dipole approximation''.<ref name=Meystre>
{{cite book
 |author=Pierre Meystre
 |title=Atom Optics
 |page=5
 |url=https://books.google.com/books?id=iULpBKHIbeoC&pg=PA5
 |isbn=978-0-387-95274-1 |year=2001
 |publisher=Springer
}}</ref><ref name= Mishchenko>
{{cite book
 | title=Light scattering by nonspherical particles
 | author=Bruce T Draine
 | chapter-url=https://books.google.com/books?id=751CbwR70KEC&pg=PA132
 | page=132
 | chapter=The discrete dipole approximation for light scattering by irregular targets
 | editor=Michael I. Mishchenko
 | year=2001
 | publisher=Academic Press
 | isbn=978-0-12-498660-2
}}</ref><ref name=Yurkin>
{{cite journal
 | title=The discrete dipole approximation: an overview and recent developments
 | author1=MA Yurkin
 | author2=AG Hoekstra
 | arxiv=0704.0038
 | journal= Journal of Quantitative Spectroscopy and Radiative Transfer
 | year=2007
 | doi=10.1016/j.jqsrt.2007.01.034
 | pages= 558–589
 | issue=1–3
 | volume=106
 | bibcode = 2007JQSRT.106..558Y
}}</ref>

==Electric dipole moments of fundamental particles==
Not to be confused with [[Spin (physics)|spin]] which refers to the [[magnetic dipole moment]]s of particles, much experimental work is continuing on measuring the electric dipole moments (EDM) of fundamental and composite particles, namely those of the [[Electron electric dipole moment|electron]] and [[Neutron electric dipole moment|neutron]], respectively. As EDMs violate both the [[parity (physics)|parity]] (P) and [[T-symmetry|time-reversal]] (T) symmetries, their values yield a mostly model-independent measure of [[CP-violation]] in nature (assuming [[CPT symmetry]] is valid).<ref>{{cite book|last1=Khriplovich|first1=Iosip B.|last2=Lamoreaux|first2=Steve K.|title=CP violation without strangeness : electric dipole moments of particles, atoms, and molecules.|date=2012|publisher=Springer|location=[S.l.]|isbn=978-3-642-64577-8}}</ref> Therefore, values for these EDMs place strong constraints upon the scale of CP-violation that extensions to the [[standard model]] of [[particle physics]] may allow. Current generations of experiments are designed to be sensitive to the [[supersymmetry]] range of EDMs, providing complementary experiments to those done at the [[LHC]].<ref>{{Cite journal|last1=Ibrahim|first1=Tarik|last2=Itani|first2=Ahmad|last3=Nath|first3=Pran|title=Electron EDM as a Sensitive Probe of PeV Scale Physics|journal=Physical Review D|volume=90|issue=5|pages=055006|date=2014 |arxiv=1406.0083|doi=10.1103/PhysRevD.90.055006|bibcode=2014PhRvD..90e5006I}}</ref>

Indeed, many theories are inconsistent with the current limits and have effectively been ruled out, and established theory permits a much larger value than these limits, leading to the [[strong CP problem]] and prompting searches for new particles such as the [[axion]].<ref>{{cite journal|last1=Kim|first1=Jihn E.|last2=Carosi|first2=Gianpaolo|title=Axions and the strong CP problem|journal=Reviews of Modern Physics|date=2010|volume=82|issue=1|pages=557–602|doi=10.1103/RevModPhys.82.557 |arxiv = 0807.3125 |bibcode = 2010RvMP...82..557K }}</ref>

==Dipole moments of molecules==
[[Dipole#Molecular dipoles|Dipole moments in molecules]] are responsible for the behavior of a substance in the presence of external electric fields. The dipoles tend to be aligned to the external field which can be constant or time-dependent. This effect forms the basis of a modern experimental technique called [[dielectric spectroscopy]].

Dipole moments can be found in common molecules such as water and also in biomolecules such as proteins.<ref name="ojeda">{{cite journal |author1=Ojeda, P. |author2=Garcia, M. |title=Electric Field-Driven Disruption of a Native beta-Sheet Protein Conformation and Generation of a Helix-Structure  |journal=Biophysical Journal |volume=99 |issue=2 |pages=595–599 |year=2010 |pmid=20643079 |pmc=2905109 |doi= 10.1016/j.bpj.2010.04.040 |bibcode = 2010BpJ....99..595O }}</ref>

By means of the total dipole moment of some material one can compute the dielectric constant which is related to the more intuitive concept of conductivity. If <math> \mathcal{M}_{\rm Tot} \,</math> is the total dipole moment of the sample, then the dielectric
constant is given by,
:<math>\epsilon = 1 + k \left\langle \mathcal{M}_\text{Tot}^2 \right\rangle</math>

where ''k'' is a constant and <math>\left\langle \mathcal{M}_\text{Tot}^2 \right\rangle = \left\langle \mathcal{M}_\text{Tot} (t = 0) \mathcal{M}_\text{Tot}(t = 0) \right\rangle</math> is the time correlation function of the total dipole moment. In general the total dipole moment have contributions coming
from translations and rotations of the molecules in the sample,
: <math>\mathcal{M}_\text{Tot} = \mathcal{M}_\text{Trans} + \mathcal{M}_\text{Rot}.</math>

Therefore, the dielectric constant (and the conductivity) has contributions from both terms. This approach can be generalized to compute the frequency dependent dielectric function.<ref name="kim">{{cite journal |author1=Y. Shim |author2=H. Kim |title=Dielectric Relaxation, Ion Conductivity, Solvent Rotation, and Solvation Dynamics in a Room-Temperature Ionic Liquid |journal=J. Phys. Chem. B |volume=112 |issue=35 |pages=11028–11038 |year=2008 |pmid=18693693 |doi=10.1021/jp802595r}}</ref>

It is possible to calculate dipole moments from [[Electronic structure|electronic structure theory]], either as a response to constant electric fields or from the density matrix.<ref>{{Cite book|title=Introduction to computational chemistry|last=Frank.|first=Jensen|date=2007|publisher=John Wiley & Sons|isbn=9780470011874|edition= 2nd|location=Chichester, England|oclc=70707839}}</ref> Such values however are not directly comparable to experiment due to the potential presence of nuclear quantum effects, which can be substantial for even simple systems like the ammonia molecule.<ref>{{Cite journal|last=Puzzarini|first=Cristina|date=2008-09-01|title=Ab initio characterization of XH3 (X = N,P). Part II. Electric, magnetic and spectroscopic properties of ammonia and phosphine|journal=Theoretical Chemistry Accounts|language=en|volume=121|issue=1–2|pages=1–10|doi=10.1007/s00214-008-0409-8|issn=1432-881X}}</ref> [[Coupled cluster|Coupled cluster theory]] (especially CCSD(T)<ref>{{Cite journal|last=Raghavachari|first=Krishnan|last2=Trucks|first2=Gary W.|last3=Pople|first3=John A.|last4=Head-Gordon|first4=Martin|title=A fifth-order perturbation comparison of electron correlation theories|journal=Chemical Physics Letters|volume=157|issue=6|pages=479–483|doi=10.1016/s0009-2614(89)87395-6|bibcode=1989CPL...157..479R|year=1989}}</ref>) can give very accurate dipole moments,<ref>{{Cite book|title=Molecular electronic-structure theory|last=Helgaker|first=Trygve|last2=Jørgensen|first2=Poul|last3=Olsen|first3=Jeppe|language=en|doi=10.1002/9781119019572|year = 2000|isbn = 9781119019572|url = http://cds.cern.ch/record/1529252|type = Submitted manuscript|publisher=Wiley}}</ref> although it is possible to get reasonable estimates (within about 5%) from [[density functional theory]], especially if [[Hybrid functional|hybrid]] or double hybrid functionals are employed.<ref>{{Cite journal|last=Hait|first=Diptarka|last2=Head-Gordon|first2=Martin|date=2018-03-21|title=How Accurate Is Density Functional Theory at Predicting Dipole Moments? An Assessment Using a New Database of 200 Benchmark Values|journal=Journal of Chemical Theory and Computation|language=en|volume=14|issue=4|pages=1969–1981|doi=10.1021/acs.jctc.7b01252|pmid=29562129|arxiv=1709.05075}}</ref> The dipole moment of a molecule can also be calculated based on the molecular structure using the concept of group contribution methods.<ref name="mueller">{{cite journal |author1=K. Müller |author2=L. Mokrushina |author3=W. Arlt |title=Second-Order Group Contribution Method for the Determination of the Dipole Moment |journal=J. Chem. Eng. Data |volume=57 |issue=4 |pages=1231–1236 |year=2012 |doi=10.1021/je2013395  }}</ref>

==See also==
{{div col|colwidth=22em}}
*[[Anomalous electric dipole moment]]
*[[Bond dipole moment]]
*[[Neutron electric dipole moment]]
*[[Electron electric dipole moment]]
*[[Multipole expansion]]
*[[Multipole moments]]
*[[Solid harmonics]]
*[[Axial multipole moments]]
*[[Cylindrical multipole moments]]
*[[Spherical multipole moments]]
*[[Laplace expansion (potential)|Laplace expansion]]
*[[Legendre polynomials]]
{{div col end}}

==References and in-line notes==
{{Reflist|36em}}

==Further reading==
*{{cite book |title=Principles of Electrodynamics |chapter=Electrical DIPOLE MOMENT  |page =49''ff'' |isbn=978-0-486-65493-5 |author=Melvin Schwartz |publisher=Courier Dover Publications |year=1987 |edition= reprint of 1972  |chapter-url=https://books.google.com/books?id=dCQiejCy1kcC&pg=PA45}}

==External links==
*[http://scienceworld.wolfram.com/physics/ElectricDipoleMoment.html Electric Dipole Moment – from Eric Weisstein's World of Physics]
*[http://www.comsol.com/community/exchange/83/ Electrostatic Dipole Multiphysics Model]{{Dead link|date=August 2019 |bot=InternetArchiveBot |fix-attempted=yes }}

[[Category:Electromagnetism]]